| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5270759 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
Terminal alkynes, under Au-catalyzed conditions, react with aromatic aldehyde diethyl acetals, affording propargylation products through CO bond addition. Furthermore, AuPPh3Cl/AgOTf-catalyzed three-component reaction of aldehydes, alkynes, and triethyl orthoformate is developed. Gold alkynilides are supposed to be reactive intermediates in these reactions.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Changkun Li, Fanyang Mo, Weibin Li, Jianbo Wang,