Article ID Journal Published Year Pages File Type
5270867 Tetrahedron Letters 2010 4 Pages PDF
Abstract

New spin probes bearing the 2,2,6,6-tetramethylpiperidine-1-yloxyl covalently bound to the imidazolium ion via a methylene spacer and an amide group are synthesized. If the anion is bis(trifluoromethylsulfonylimide) instead of iodide, the new spin probe has a similar structure as that of an ionic liquid. Nevertheless, the new spin probes are useful tools to investigate ionic liquids.

Graphical abstractCovalent bonding of a spin probe to the imidazolium ion via an acetamido group opens the possibility to detect the mobility of the ionic liquid cation by ESR spectroscopy.Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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