Article ID Journal Published Year Pages File Type
5270959 Tetrahedron Letters 2009 5 Pages PDF
Abstract

Retro iminonitroso Diels-Alder reactions were investigated in both solution and solid phase. In thermal or Cu(I)-mediated reactions, interconversion of various nitroso cycloadducts occurred in the presence of separate dienes. Up to 99% of conversion was observed. Use of chiral ligands in the Cu(I)-mediated reactions gave new cycloadducts enantioselectively.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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