Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5270990 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
Studies on the synthesis of racemic tragoponol are described. The western resorcylate unit of tragoponol was efficiently constructed from appropriate diketo-dioxinone and secondary alcohol intermediates using a ketene generation-trapping and aromatization sequence. Further functionalization provided an advanced diketo-dioxinone intermediate which upon desilylation resulted in the formation of a dihydroisocoumarin.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hideki Miyatake-Ondozabal, Anthony G.M. Barrett,