Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5271010 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
Diaminomethylenemalononitrile organocatalyst 5 promotes the asymmetric conjugate addition of branched aldehydes to vinyl sulfone to afford the corresponding adducts with all-carbon quaternary stereocenters in excellent yields with up to 91% ee.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yohei Kanada, Hiroki Yuasa, Kosuke Nakashima, Miho Murahashi, Norihiro Tada, Akichika Itoh, Yuji Koseki, Tsuyoshi Miura,