Article ID Journal Published Year Pages File Type
5271210 Tetrahedron Letters 2013 4 Pages PDF
Abstract

A new internal charge transfer (ICT) based colorimetric as well as fluorogenic sulfur-free probe for highly selective and sensitive monitoring of Hg2+ has been developed and reported in this Letter. It gives a colorimetric and fluorometric response upon addition of Hg2+ in acetonitrile:water (1:1) solution at a physiological pH, with no significant interference of other competitive metal ions. Receptor (TPM) shows a distinct color change from light yellow to orange upon progressive addition of Hg2+, so that it can serve as a naked-eye sensor for Hg2+ ion. It exhibits excellent reproducibility, reversibility, and selectivity with the detection limit at micro-molar level.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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