Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5271922 | Tetrahedron Letters | 2013 | 6 Pages |
Abstract
A facile synthesis of benzofulvenes was carried out starting from the Morita-Baylis-Hillman adducts of 2-bromobenzaldehyde. The synthesis was carried out via the sequential bromination, Wittig reaction with aldehyde, and Pd-catalyzed intramolecular Mizoroki-Heck reaction. The stereochemistry of benzofulvenes was dependent on the reaction condition, especially on the kinds of base and reaction time, and the substituent of starting materials.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Cheol Hee Lim, Ko Hoon Kim, Jin Woo Lim, Jae Nyoung Kim,