| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5272044 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
Radical-mediated thiodesulfonylation of the vinyl and (α-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (α-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of the stereochemistry of the starting vinyl sulfones.
Graphical abstractRadical-mediated thiodesulfonylation of the vinyl and (α-fluoro)vinyl sulfones provides vinyl and (α-fluoro)vinyl sulfides.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Pablo R. Sacasa, Jessica Zayas, Stanislaw F. Wnuk,