| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5272063 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
Methylation of t-butyl-1-dimethylphosphono-2-p-tolylsulfinyl cyclopropanecarboxylic ester occurs with full inversion of the configuration, but the stereochemistry of carbanion formation is structure-dependent. Reaction of cyclopropyl sulfoxide with i-PrMgCl leads to unprecedented 1,2 migration of the phosphoryl group.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Wanda H. Midura, Agata Sobczak, Piotr Paluch,