| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5272274 | Tetrahedron Letters | 2012 | 5 Pages |
Abstract
An efficient epoxide to carbonyl rearrangement using catalytic AuCl3/AgSbF6 has been presented. The reactions are fast and high yielding. β-Hydrogen migration takes place exclusively when hydrogen and methyl or substituted methyl groups are present at β-carbon of epoxide. When phenyl/acetyl/benzoyl and hydrogen are available at same carbon atom, migration of the former is preferred over the latter.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Vanajakshi Gudla, Rengarajan Balamurugan,