| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5272336 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
Stereocontrolled synthesis of a fully functionalized AB ring moiety of fomitellic acids was accomplished. The tricyclic skeleton was stereoselectively constructed by means of titanium(III)-mediated radical cascade cyclization of epoxypolyene. The stereochemistry at C1 and C3 was controlled by a vinylogous Mukaiyama aldol reaction and a Sharpless asymmetric epoxidation, respectively.
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