| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5272595 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
Palladium-catalysed Suzuki-Miyaura cross-coupling proved to be the simplest and most efficient method for attaching an unsubstituted allene, a novel substituent and potential functional group, to the porphyrin periphery. Comparative studies on various allenyl synthetic pathways show that this method, which makes use of a bromoporphyrin and allenylboronate, affords the corresponding allenylporphyrin in the presence of an appropriate base and THF.
Graphical abstractPalladium-catalysed Suzuki-Miyaura cross-coupling is the simplest and most efficient method for attaching an unsubstituted allene, a novel substituent and potential functional group, to the porphyrin periphery.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Oliver B. Locos, Katja Dahms, Mathias O. Senge,