Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5272766 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
In the superacidic media HF/SbF5, hydroxylation of several Tröger's bases was performed using sodium persulfate as a hydroperoxonium H3O2+ precursor. The obtained products are selectively hydroxylated in good yields on unusual positions of the aromatic rings.
Graphical abstractIn HF/SbF5, Tröger's bases have been selectively hydroxylated in good yields on aromatic rings, using sodium persulfate as hydroperoxonium H3O2+ precursor.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Emilie Vardelle, Agnès Martin-Mingot, Marie-Paule Jouannetaud, Jean-Claude Jacquesy, Jérôme Marrot,