Article ID Journal Published Year Pages File Type
5272840 Tetrahedron Letters 2009 4 Pages PDF
Abstract

The utility of zinc selenolates for effecting nucleophilic cleavage of simple lactones and esters has been investigated. When zinc selenolate generated via Zn/AlCl3-promoted cleavage of diselenides was reacted with simple lactones and esters, efficient nucleophilic alkyl-oxygen bond cleavage proceeded generating the corresponding carboxylic acids in moderate to excellent yields.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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