| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5272876 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
The enantioselective ring-opening reaction of meso-epoxides with aryl thiols catalyzed by a chiral heterobimetallic Ti-Ga-Salen complex was realized, and the 1,2-mercapto alcohols were obtained in good yields and moderate to high enantioselectivities (up to 92% ee). A strong synergistic cooperation between different Lewis acids in the system was exhibited in the catalytic process.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jiangtao Sun, Fang Yuan, Minghua Yang, Yi Pan, Chengjian Zhu,