Article ID Journal Published Year Pages File Type
5273003 Tetrahedron Letters 2008 5 Pages PDF
Abstract

Cascade reaction involving reductive cyclization, Dieckmann condensation, and lactonization of E- and Z-dimethyl 2-methyl-8-oxoundec-2-enedioates and Z-dimethyl 2-methyl-7-oxodec-2-enedioate with samarium(II) iodide was found to stereospecifically produce cis and trans bicyclo[4.4.0]decane (decalin) ring systems and trans bicyclo[4.3.0]nonan (perhydroindane) ring system each consisting of γ-lactone, respectively.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry