Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5273226 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
An easy approach to mono- and bicyclic derivatives of 5,6-dihydro-1H-pyridine-2-thione via a one-pot ring closing metathesis (RCM) of dialkenoic amides and thionation using Lawesson's reagent, followed by isomerization of the 3,6-dihydro-isomer (if necessary), is described. The appreciable differences in the reactivity of diallylic amides in RCM reactions are discussed.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jacek G. SoÅnicki,