| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5273297 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
The still unknown parent tetrathiafulvalene-terpyridine- ligand 5 (namely TTF-terpy), was synthesized through a straightforward strategy. The dyad exhibits an intramolecular charge transfer (ICT) which was evidenced by UV-vis electronic absorption. Complexation of various transition metal cations by this redox-active ligand was studied by UV-vis absorption spectroscopy as well as by cyclic voltammetry titration studies, supporting the dual functional character of this system. In addition, these results demonstrate that ligand 5 is a suitable building block for the preparation of electroactive neutral as well as charged metal complexes.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Esmah Belhadj, Abdelkrim El-Ghayoury, Miloud Mazari, Marc Sallé,