Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5273394 | Tetrahedron Letters | 2010 | 4 Pages |
Abstract
Syntheses of several (sulfonyl)methylphosphonate analogs of geranyl, neryl, and farnesyl diphosphates are described. Key steps include utilization of an (E)-selective Horner-Wadsworth-Emmons olefination which couples an aldehyde to the sulfone phosphonate moiety, and a selective reduction of the resulting dienyl sulfone phosphonate substrates.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Michael W. Lodewyk, Victor G. Lui, Dean J. Tantillo,