Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5273754 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
Four tridentate [C,N,S] thiosemicarbazone Pd(II) complexes were applied as catalyst precursors for the Suzuki-Miyaura coupling of a variety of aryl halides and aryl boronic acids. After screening various catalytic conditions, it was found that one dinuclear complex IV containing the bis(diphenylphosphino) ferrocene spacer was able to efficiently catalyze these reactions with yields up to 99% irrespective of the type of aryl substituent on the substrate.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hong Yan, Prinessa Chellan, Tingyi Li, Jincheng Mao, Kelly Chibale, Gregory S. Smith,