Article ID Journal Published Year Pages File Type
5273958 Tetrahedron Letters 2008 4 Pages PDF
Abstract

The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc)2/DPPE and [Pd(π-allyl)(cod)]BF4/DPPF. The selective formation of the γ-product was attained by Pd(OAc)2/DPPE, while the α-product was obtained using [Pd(π-allyl)(cod)]BF4/DPPF.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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Regioselective synthesis of trifluoromethyl group substituted allylic amines via palladium-catalyzed allylic amination
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