| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5273980 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
Cu(I)-catalyzed Huisgen-Meldal-Sharpless type dipolar 'click' reactions between azido-tetrathiafulvalene derivatives and ethynylferrocene yield the first examples of ferrocenyl-1,2,3-triazolyl-tetrathiafulvalene assemblies (4a, 4b). The electrochemical behavior of 4a and 4b, which integrate two distinctive redox probes, has been investigated, and their binding ability for various transition-metal cations has been studied by cyclic voltammetry. The contribution of the triazolyl ring in the guest binding process is illustrated by the specific electrochemical recognition of Zn2+ by receptor 4b.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Bang-Tun Zhao, Lian-Wei Liu, Xiao-Chuan Li, Gui-Rong Qu, Esmah Belhadj, Franck Le Derf, Marc Sallé,