| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5274026 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
Gymnastatins F (1) and Q (2) were successfully synthesized using the tandem Michael and aldol reaction of the corresponding spirodienones with hemiacetal functions. Inspection of the optical purities of the substrates suggested that undesired racemization does not proceed during the tandem reaction. Results of theoretical calculations agreed with the ratio of the reaction outcome.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kyoko Murayama, Takamasa Tanabe, Yuichi Ishikawa, Kensuke Nakamura, Shigeru Nishiyama,