Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5274105 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first anti enantioselective desymmetrization with aromatic nucleophiles is reported.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Renaud Millet, Tania Bernardez, Laëtitia Palais, Alexandre Alexakis,