Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5274318 | Tetrahedron Letters | 2012 | 5 Pages |
Abstract
A new method is described for the oxidative chlorination of thiols to sulfonyl chlorides using titanium tetrachloride in combination with the oxidant hydrogen peroxide. Direct conversion of thiols into their corresponding thiosulfonates is also reported. Good to excellent yields, short reaction times, high efficiencies, cost-effectiveness, and, facile isolation of the desired products make the present methodology a practical alternative.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kiumars Bahrami, Mohammad M. Khodaei, Donya Khaledian,