Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5274333 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
The first palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts is described. A variety of cyclic and acyclic vinyl tosylates were coupled with aryl sulfinate salts using 2.5 mol % Pd2(dba)3/5.0 mol % XantPhos to give vinyl aryl sulfone products in good yields. The coupling was extended to the preparation of a cyclopropyl vinyl sulfone.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Diana C. Reeves, Sonia Rodriguez, Heewon Lee, Nizar Haddad, Dhileep Krishnamurthy, Chris H. Senanayake,