Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5274650 | Tetrahedron Letters | 2008 | 5 Pages |
Abstract
Cyclic ethers are cleaved in the presence of nitromethane, a base, a hypervalent iodine compound and a Rh(II) catalyst to give nitromethoxy acetates in up to 71% isolated yields. The reaction is a three-component coupling of an ether with a nitromethane derived carbenoid and a carboxylate group originating from the hypervalent iodine compound.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hanne Therese Bonge, Tore Hansen,