Article ID Journal Published Year Pages File Type
5274650 Tetrahedron Letters 2008 5 Pages PDF
Abstract

Cyclic ethers are cleaved in the presence of nitromethane, a base, a hypervalent iodine compound and a Rh(II) catalyst to give nitromethoxy acetates in up to 71% isolated yields. The reaction is a three-component coupling of an ether with a nitromethane derived carbenoid and a carboxylate group originating from the hypervalent iodine compound.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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