| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5274654 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
An efficient synthesis of fluorocyclopentenes is described. By treatment of (2-fluoroalkenyl)iodonium salts with potassium tert-butoxide, (α-fluoroalkylidene)carbenes were generated efficiently to give fluorocyclopentenes via 1,5-C-H insertion. Fluorocyclopentenes having a functionality, such as chlorine, acetoxy, or ketone, and a spiro fluorocyclopentene were synthesized in good yields.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Tong Guan, Kohei Takemura, Hisanori Senboku, Masanori Yoshida, Shoji Hara,