Article ID Journal Published Year Pages File Type
5274662 Tetrahedron Letters 2008 4 Pages PDF
Abstract

An efficient and environmentally benign boric acid catalyzed protocol for the transesterification of ethyl acetoacetate with a variety of primary and secondary alcohols in good to excellent yields is described. The versatility of this transformation is demonstrated with problematic substrates such as propargyl alcohol and allyl alcohol, which are known to undergo Carroll rearrangement during transesterification.

Graphical abstractBoric acid catalyzed efficiently transesterification of ethyl acetoacetate with a variety of primary and secondary alcohols.Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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