Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5274709 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one can recognize three different metal cations Cu2+, Ag+ and Hg2+ via naked eye visualization, and shows turn-on fluorescence for Fe3+ and Ag+ among the 22 metal cations.
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