| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5274722 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
The palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions were successfully carried out under irradiation with sunlight. The Heck reaction gives considerable amount of Z product due to photochemical isomerization of initially formed E alkenes. Reaction of methyl 2-iodobenzoate with acrylamide under solar condition furnished 2H-2-benzazepine-1,3-dione rather than the expected derivative of cinnamate while the same reaction with ethyl 2-iodobenzoate gave the desired cinnamide.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Anju R. Chaudhary, Ashutosh V. Bedekar,