| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5274748 | Tetrahedron Letters | 2011 | 6 Pages |
Abstract
Proton-exchanged montmorillonite showed catalytic activity for intermolecular allylsilylation, arylsilylation, and terminal silylation of alkynes with allylsilanes. The reaction selectivity greatly depended on the solvent used. Reactions proceeded with various terminal alkynes and allylsilanes in good to moderate yields. The reaction pathways involving cationic Si species on the montmorillonite surface were also investigated.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ken Motokura, Shigekazu Matsunaga, Akimitsu Miyaji, Tatsuaki Yashima, Toshihide Baba,