Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5274767 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
Diazoketone derivatives of meso 8-oxabicyclo[3.2.1]octen-3-ones were desymmetrized by an intramolecular C-H insertion mediated by chiral copper and dirhodium catalysts to generate oxatricyclic systems with up to 5 contiguous stereogenic centres and 50% ee.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xiaomei Zhang, Zhengning Li, John C.K. Chu, Pauline Chiu,