Article ID Journal Published Year Pages File Type
5274936 Tetrahedron Letters 2007 5 Pages PDF
Abstract

A new binaphthalene (R)-1 with two substituted TTF and trichloroquinone units is reported. Both absorption and ESR spectral studies show that electron transfer occurs between TTF and trichloroquinone units of (R)-1 in the presence of metal ions (Pb2+, Sc3+, Zn2+, and Ca2+). We also propose a possible mechanism for this electron transfer process. But, the CD spectral change of (R)-1 in the presence of metal ions is rather small.

Graphical abstractElectron transfer between TTF and quinone units of a substituted binaphthalene was observed in the presence of metal ions (Pb2+, Sc3+, Zn2+, and Ca2+).Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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