| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275079 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
A stereoselective method for the preparation of dibenzoxapine containing tetrasubstituted exocyclic E-alkenes has been developed. The key reaction involves an intramolecular cyclocarbopalladation of alkynes to form a vinylpalladium species and subsequently coupling the vinylpalladium with methylboronic acid. The approach provides a straightforward method for the synthesis of tetrasubstituted exocyclic E-alkenes.
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Authors
Hannah Yu, Rachel N. Richey, Javier Mendiola, Marta Adeva, Carmen Somoza, Scott A. May, Matthew W. Carson, Michael J. Coghlan,