| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275146 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
(2,6-Dimethoxyphenyl)-dimethylsilyl group constitutes a new orthogonal masked hydroxyl group. Protodesilylation of this arylsilane occurs under photochemical conditions in the presence of alcohols such as hexafluoroisopropanol (HFIP) or isopropanol. These mild and neutral conditions thus allowed the oxidation of organosilicon compounds such as β-hydroxysilanes that are known to be prone to Peterson elimination.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Susen Werle, Frédéric Robert, Henri Bouas-Laurent, Yannick Landais,