| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275149 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Ketone zincate-type enolates can be applied to radical trifluoromethylation for the general synthesis of α-CF3-ketones, cyclopentanones in particular. The addition of diethylzinc to lithium enolates is the key in the preparation of the zincate-type enolates for efficient radical trifluoromethylation.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yuichi Tomita, Yoshiyuki Ichikawa, Yoshimitsu Itoh, Kosuke Kawada, Koichi Mikami,