Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275171 | Tetrahedron Letters | 2012 | 4 Pages |
The reaction of different 7,8-disubstituted coumarin 4-acetic acids with 7-diethylaminocoumarin-3-carbaldehyde in the presence of piperidine in methanol gives highly fluorescent (E)-1-(7-diethylaminocoumarin-3-yl)-2-(7,8-disubstituted coumarin-4-yl)ethenes in good yield. Only the (E) diastereomers of these are obtained. The compounds are new, orange to red in colour and show emission in yellow to red region. These compounds were further studied for their emission properties.
Graphical abstractThe reaction of different 7,8-disubstituted coumarin 4-acetic acids with 7-diethylaminocoumarin-3-carbaldehyde in the presence of piperidine in methanol gives highly fluorescent (E)-1-(7-diethylaminocoumarin-3-yl)-2-(7,8-disubstituted coumarin-4-yl)ethenes in good yield. Only the (E) diastereomers of these are obtained. The compounds are new, orange to red in colour and show fluorescence in yellow to red region. These compounds were further studied for their fluorescence properties.Download full-size image