| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275213 | Tetrahedron Letters | 2009 | 5 Pages |
Abstract
A facile and direct highly stereoselective synthesis of [E]- and [Z]-allyl dithiocarbamates has been accomplished from acetates of Baylis-Hillman (BH) adducts in catalyst-free one-pot three-component coupling reactions of carbon disulfide and amine in water under a mild and green procedure with high yields. The reaction pathway involves the nucleophilic displacement (SN2â²) of BH acetates by dithiocarbamate anions. The utility of these allyl dithiocarbamates has also been demonstrated in heterocyclic chemistry. © 2009 Elsevier Science. All rights reserved
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Lal Dhar S Yadav, Rajesh Patel, Vishnu P. Srivastava,