| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275299 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
A new addition reaction of a 3-alkoxy allenylzinc reagent to N-acyliminiums prepared in situ from imines and acid halides is reported. Unlike addition onto imines or nitrones that affords the trans adducts, acetylenic syn-1,2 amino ethers are yielded with good selectivities, thus providing a new entry to propargyl syn-1,2-aminoalcohol units.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Brindaban Roy, Alejandro Pérez-Luna, Franck Ferreira, Candice Botuha, Fabrice Chemla,