Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275350 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The photostimulated reaction of N-(2-halo-benzyl)aryl amines with t-BuOK in liquid ammonia affords fused azaheterocycles by the SRN1 mechanism. The starting materials are easily obtained by the reaction of 2-halo-benzyl chloride and aromatic amines to prepare the secondary amines. Through this approach, phenanthridine (90%), 4-phenylphenanthridine (87%), benzo[a]phenanthridine (98%), and benzo[c]phenanthridine (84%) were synthesized.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Maria E. Budén, Roberto A. Rossi,