Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275426 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
The discovery that supporting electrolytes can be effectively confined in typical organic solvents in a c-Hex-based multiphase electrolyte solution has led to the development of a novel heterogeneous continuous flow synthetic system. PTFE fiber functions as a separation filter that can efficiently isolate the c-Hex phase from multiphase electrolyte solutions. This system has demonstrated both electrochemical solvating and carbon-carbon bond forming reactions. Hydrophobic substrates can be introduced into the reactor as c-Hex solutions, which are then electrochemically transformed into the target hydrophobic products that pass through the PTFE fiber as c-Hex solutions.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yohei Okada, Tomohiko Yoshioka, Mikio Koike, Kazuhiro Chiba,