Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275495 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
A chiral scandium-bipyridine complex catalyzes the highly enantioselective addition of phenylselenol to aromatic meso-epoxides and furnishes 1,2-seleno alcohols in good yields and up to 94% ee. In addition, a sequential, one-pot epoxide opening-reduction protocol has been developed for the direct synthesis of 1,2-diaryl carbinols.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Andreas Tschöp, Mecheril Valsan Nandakumar, Oksana Pavlyuk, Christoph Schneider,