| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275522 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The first asymmetric synthesis of (+)-iso-6-cassine is described. Lipase-catalyzed resolution, enantioselective Overman rearrangement, and diastereoselective intramolecular amidomercuration were used for the installation of the three stereocenters in (+)-iso-6-cassine, and cross-metathesis was employed for the attachment of the side-chain.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Satwinder Singh, Om V. Singh, Hyunsoo Han,