| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275528 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Nitration of asymmetric hydrazones with nitric oxide occurred stereoselectively at C1′-atom, giving mono-nitrated trans isomer as a major outcome. The ratio of trans to cis was up to >99. Higher isolated yields of nitrated products and higher trans/cis ratios of isomers suggest that this procedure offers advantages for synthesizing asymmetry nitro compounds.
Graphical abstractNitration of asymmetric hydrazones with nitric oxide occurred stereoselectively, giving mono-nitrated trans isomer as a major outcome. The ratio of trans to cis was up to >99.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
