| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275583 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
We developed an iterative synthetic method for oligo-aryl compounds using an organosilicon-based palladium-catalyzed cross-coupling reaction. Aryl compounds containing a benzyloxy(diisopropyl)silyl group (masked Si group) had sufficient chemical stability, and the unmasking step proceeded in a high yield under mild conditions. Both of the key unmasking/coupling steps required no strict anhydrous or degassed conditions. The developed procedure was used for the synthesis of thiophene-based organic dyes for dye-sensitized solar cells.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
