Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275623 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
We have developed a new chemosensor system for cyanide ion that is based on a photochromic material. We observed that addition of cyanide anion to a UV irradiated solution of a phenoxynaphthacenequinone derivative brought about a significant change in the absorption spectra that enabled detection of cyanide ion in a selective and sensitive manner. A carbanion intermediate was shown to be responsible for the long wavelength absorption band (630-940Â nm) that is generated by cyanide addition.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
In Sung Park, Eun-Joo Heo, Jong-Man Kim,