Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275716 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
A general method has been developed for the stereoselective construction of 2,6-disubstituted dihydropyrans based on the Lewis acid-catalyzed intramolecular reactions of oxocarbenium ions with vinylstannanes. This novel methodology was applied to the enantioselective total synthesis of (−)-centrolobine.
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