| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5275917 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The decarboxylative Claisen rearrangement of a range of substituted diallyl 2-sulfonylmalonates is described. The substrates are made by C-carboxylation of the corresponding allyl sulfonylacetates with allyl para-nitrophenyl carbonates. The reactions display a high degree of regioselectivity, with allylic substituents possessing electron-rich substituents at the allyl three-position rearranging preferentially.
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