Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5275920 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
New adamantane-dipyrromethanes (AdD 1-4) were synthesized and their anion binding properties investigated. AdD 1-3 form 2:1 complexes with Fâ (AdD:FÂ =Â 2:1) characterized by high association constants, and 1:1 complexes with Clâ, Brâ, HSO4- and H2PO4-. The binding of Clâ, Brâ, HSO4-and H2PO4- by AdD 1-3 is 2-3 times stronger than for the reference compound, meso-phenyldipyrromethane (5). However, AdD 4 forms complexes with Fâ characterized by 1:1 and 1:2 stoichiometry (AdD:FÂ =Â 1:2).
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Marija ReniÄ, Nikola BasariÄ, Kata MlinariÄ-Majerski,